Burn your cue/bin files with CDRWin or Fireburner as they are decigned for it.
Also, not all DVD players can play VCD's, check at _http://www.vcdhelp.com/dvdplayers.php for your player. A lot of conflicting data there but read all the comments. Some units will play using certain brands of CDR or CDRW only. Many more play VCD's burnt to CDRW's so try one of those.